Molecular Formula | C7H10O3S |
Molar Mass | 174.22 |
Density | 1.244 |
Boling Point | 285℃ |
Flash Point | 137℃ |
Appearance | Liquid or Solid |
Color | Clear colorless to pale yellow |
Storage Condition | Sealed in dry,Room Temperature |
Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin. |
Safety Description | S23 - Do not breathe vapour. S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection. |
HS Code | 29349990 |
Use | Tetrahydro-4-oxo-2H-thian-3-methyl formate is a carboxylate derivative that can be used as an organic intermediate. |
preparation | dimethyl 3,3 '-thiodipropionate (1130.0g,630.3mmol) and NaH(60%,22.7g,945.5mmol) were added to a flask containing 500mL tetrahydrofuran. Stir the mixture at room temperature for 4h. After the reaction, the above mixture was added to 1000mL of water and extracted with dichloromethane several times. The obtained organic phase was dried with anhydrous sodium sulfate, and methylene chloride was recovered under reduced pressure to obtain methyl tetrahydro-4-oxo-2H-thian-3-formate, yellow liquid 104.3g, and the yield was 95.0%. |